The possibility of removal of metal ions from mining waste waters thro
ugh ion flotation is investigated. Waste water of an opencast mine con
taining about 50 mg/l copper ions is purified. The ions undergo precip
itation with xanthates forming chelate complexes with high hydrophobic
ity. Electroflotation is used for the obtaining of a gaseous phase wit
h sufficient volume and high dispersity. Conditions are established fo
r the realization of the precipitation and adsorbing colloid mechanism
of flotation. An active potassium oleate surfactant is used for the s
tabilization of foam formation and for the improvement of the precipit
ation with the main precipitant. Removal of the metal ions present in
the waste water is achieved.