Se. Haggerty et al., APATITE, PHOSPHORUS AND TITANIUM IN ECLOGITIC GARNET FROM THE UPPER-MANTLE, Geophysical research letters, 21(16), 1994, pp. 1699-1702
The existence of apatite exsolution lamellae in garnet supports earlie
r suggestions that garnet is a major repository for P in the mantle, a
nd that P is strongly coupled to Na+Ti. The bulk P content (approximat
ely 250 ppm) of mantle eclogites is unexpectedly similar to estimates
for the P content (130-220 ppm) of the upper mantle; both rocks are de
pleted relative to chondrites and to ocean floor basalts. Eclogites ha
ve either equilibrated with the mantle at large, or have undergone sec
ondary melting, and based on P contents are unlikely to have had subdu
cted protoliths.