PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-2-PHENYLPROPIONIC ACID OR (R)-2-PHENYLPROPIONIC ACID -THE MAGNETIC-FIELD AND SOLVENT EFFECTS AND CHIRAL-SYMMETRY BREAKING -COMMENT

Authors
Citation
R. Nakagaki, PHOTOCHEMICAL-REACTION OF 4-METHYL-2-QUINOLINECARBONITRILE WITH OPTICALLY-ACTIVE (S)-2-PHENYLPROPIONIC ACID OR (R)-2-PHENYLPROPIONIC ACID -THE MAGNETIC-FIELD AND SOLVENT EFFECTS AND CHIRAL-SYMMETRY BREAKING -COMMENT, Chemical physics, 185(3), 1994, pp. 405-411
Citations number
33
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
185
Issue
3
Year of publication
1994
Pages
405 - 411
Database
ISI
SICI code
0301-0104(1994)185:3<405:PO4WO>2.0.ZU;2-C
Abstract
R-(-)- and S-(+)-2-phenylpropionic acids exhibit equivalent reactivity toward the excited state of 4-methyl-2-quinoline-carbonitrile carboni trile in acetonitrile. No significant magnetic field effects were obse rved upon the relative quantum yield for photochemical reactions betwe en the quinolinecarbonitrile with the optically active 2-phenylpropion ic acids in benzene. No unusual phenomena were observed under well con trolled conditions with sufficient repetitions.