TETRAKIS-(4-METHOXYPHENYL)PORPHINATO-BIS(TRIMETHYL PHOSPHITO)IRON(II)

Authors
TOUPET L LEGRAND N BONDON A SIMONNEAUX G
Citation
L. Toupet et al., TETRAKIS-(4-METHOXYPHENYL)PORPHINATO-BIS(TRIMETHYL PHOSPHITO)IRON(II), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1014-1016
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
7
Pages
1014 - 1016
Database
ISI
SICI code
0108-2701(1994)50:<1014:TP>2.0.ZU;2-T
Abstract
The structure determination of the title compound, 23),9,11,13,15,17,1 9-undecaenediido-N,N',N'',N'''} bis(trimethyl phosphito-P)iron(II), [F e(C48H36N4)(C3H9O3P)2], is the first example of a structural study on a model phosphito ferrous porphyrin derivative. The complex crystalliz es in a centrosymmetric form. The metal-phosphorus bond lengths [2.255 (2) angstrom] are shorter than those observed in the analogous iron(I I) complex containing dimethylphenylphosphine ligands [2.284 (1) angst rom].