-3-ETHOXY(N-METHYLIMINO)-METHANETHIOLATO)COPPER(I)

Authors
KURODASOWA T MUNAKATA M MIYAZAKI M MAEKAWA M
Citation
T. Kurodasowa et al., -3-ETHOXY(N-METHYLIMINO)-METHANETHIOLATO)COPPER(I), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1026-1028
Citations number
10
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
7
Pages
1026 - 1028
Database
ISI
SICI code
0108-2701(1994)50:<1026:->2.0.ZU;2-#
Abstract
mino)methane-thiolato]-1kappaN,2:4kappa2S,2kappaN, 1:3kappa2S;3kappaN, 1:4kappa2S;4kappaN,-2:3kappa2S-tetracopper, [Cu2(C4H8NOS)2]2, contain s a tetrahedral Cu, core surrounded by four effectively tridentate eth oxy(N-methylimino)methanethiolato (or O-ethyl N-methylcarbonimidothioa to) ligands, CH3N=C(OC2H5)S-. Each Cu atom is coordinated by an N atom and two S atoms in a trigonal planar environment. There are two kinds of Cu(I)-Cu(I) distances (average 2.616 and 2.845 angstrom), resultin g in a butterfly structure for the Cu4 core.