PYRIMIDINYLTHIOMETHYL)PYRIDINE]-DICHLOROCOPPER(II) METHANOL SOLVATE

Authors
SILLANPAA R KIVEKAS R ESCRICHE L CASABO J SANCHEZCASTELLO G
Citation
R. Sillanpaa et al., PYRIMIDINYLTHIOMETHYL)PYRIDINE]-DICHLOROCOPPER(II) METHANOL SOLVATE, Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1062-1064
Citations number
5
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
7
Pages
1062 - 1064
Database
ISI
SICI code
0108-2701(1994)50:<1062:PMS>2.0.ZU;2-8
Abstract
In the title compound, [CuCl2(C15H13N5S2)].CH3OH, the Cu2+ ion has squ are-pyramidal coordination geometry. The basal plane of the pyramid is formed by two Cl- ions, one pyridine N atom and one pyrimidine N atom . The fifth coordination site is occupied by the S atom of a thiomethy l group. The methanol molecule occupies an otherwise empty space in th e structure.