LMETHYLIDENE)-2-THIENYLMETHYLAMINE-N,N']COPPER(II) AND METHYLIDENE)-2-THIENYLMETHYL-AMINE-N,N']COPPER(II) COMPLEXES, [CUCL2(C11H10N2S)] AND[CUBR2(C11H10N2S)]

Citation
Am. Atria et al., LMETHYLIDENE)-2-THIENYLMETHYLAMINE-N,N']COPPER(II) AND METHYLIDENE)-2-THIENYLMETHYL-AMINE-N,N']COPPER(II) COMPLEXES, [CUCL2(C11H10N2S)] AND[CUBR2(C11H10N2S)], Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1066-1069
Citations number
3
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
7
Pages
1066 - 1069
Database
ISI
SICI code
0108-2701(1994)50:<1066:LAM>2.0.ZU;2-1
Abstract
The crystal structures of dichloro- (2) and lmethylidene)-2-thienylmet hylamine-N,N']copper(II) (1) have been determined to investigate the c oordination of die metal centre. In both cases, the two N atoms and tw o halogen anions are coordinated to the copper(II) and the S atom is f ree. For the dibromo complex, the structure is monomeric, while die di chloro complex forms dimers diylidene)-2-thienylmethyl-amine-N,N']copp er(II)})