REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)]

Authors
ANG HG KWIK WL ONG KK
Citation
Hg. Ang et al., REACTION OF PENTAFLUORONITROSOBENZENE WITH [OS3H(MU-H)(CO)10(MPH3)] (M=P, AS, SB) - SYNTHESIS AND X-RAY STRUCTURE OF [OS3(MU-H)(CO)10(PPH3)(ONC6F4O)], Journal of organometallic chemistry, 474(1-2), 1994, pp. 149-152
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
474
Issue
1-2
Year of publication
1994
Pages
149 - 152
Database
ISI
SICI code
0022-328X(1994)474:1-2<149:ROPW[(>2.0.ZU;2-2
Abstract
The pentafluoronitrosobenzene C6F5NO has been shown from infrared spec tral, F-19 NMR spectral and single-crystal X-ray diffraction studies t o undergo oxidation at the para-position upon reaction with [Os3H(mu-H )(CO)10(PPh3)] to afford [Os3(mu-H)(CO)10(PPh3)(ONC6F4O)](I). The arse nic- and stibine- analogues of I ([Os3(mu-H)(CO)10(MPh3)(ONC6F4O)) (M = As, Sb)) were also isolated.