THE FORMATION OF DISTANNANES FROM TIN HYDRIDES

Authors
DAVIES AG OSEIKISSI DK
Citation
Ag. Davies et Dk. Oseikissi, THE FORMATION OF DISTANNANES FROM TIN HYDRIDES, Journal of organometallic chemistry, 474(1-2), 1994, pp. 30000008-30000010
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
474
Issue
1-2
Year of publication
1994
Pages
30000008 - 30000010
Database
ISI
SICI code
0022-328X(1994)474:1-2<30000008:TFODFT>2.0.ZU;2-B
Abstract
The disproportionation of a dialkyltin hydride R2SnXH (X = halide or c arboxylate) to give H-2 and XR2SnSnR2X follows a radical chain mechani sm, which may involve homolytic displacement by a tin radical of a hyd rogen atom from a tin centre.