HYDROSTANNATION AND HYDROSTANNOLYSIS BY DIORGANOTIN HYDRIDES R2SNXH (X = HALIDE, CARBOXYLATE, SULFONATE, ETC)

Citation
Ag. Davies et al., HYDROSTANNATION AND HYDROSTANNOLYSIS BY DIORGANOTIN HYDRIDES R2SNXH (X = HALIDE, CARBOXYLATE, SULFONATE, ETC), Journal of organometallic chemistry, 474(1-2), 1994, pp. 30000011-30000013
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
474
Issue
1-2
Year of publication
1994
Pages
30000011 - 30000013
Database
ISI
SICI code
0022-328X(1994)474:1-2<30000011:HAHBDH>2.0.ZU;2-J
Abstract
Diorganotin halide hydrides or carboxylate hydrides, R2SnXH, will brin g about the hydrostannolysis of alkyl halides, or the hydrostannation of alkynes or of carbonyl compounds at or below room temperature. The reactions show different chemo-, regio-, and stereo-selectivities from those involving tributyltin hydride.