TRANSFER OF THE (DITHIOMETHYOXYCARBONYL)DIPHENYLPHOSPHINE LIGAND FROMTUNGSTEN TO PALLADIUM - SYNTHESES AND CRYSTAL-STRUCTURES OF 2 PALLADIUM (DITHIOMETHOXYCARBONYL)PHOSPHINE COMPLEXES

Authors
YIH KH LIN YC CHENG MC WANG Y
Citation
Kh. Yih et al., TRANSFER OF THE (DITHIOMETHYOXYCARBONYL)DIPHENYLPHOSPHINE LIGAND FROMTUNGSTEN TO PALLADIUM - SYNTHESES AND CRYSTAL-STRUCTURES OF 2 PALLADIUM (DITHIOMETHOXYCARBONYL)PHOSPHINE COMPLEXES, Journal of organometallic chemistry, 474(1-2), 1994, pp. 30000034-30000036
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
474
Issue
1-2
Year of publication
1994
Pages
30000034 - 30000036
Database
ISI
SICI code
0022-328X(1994)474:1-2<30000034:TOT(LF>2.0.ZU;2-F
Abstract
The (dithiomethoxycarbonyl)phosphine transfer reaction between Pd(PPh3 )4 and W(CO)5[PPh2(CS2Me)], 1, forms {Pd(PPh3)[mu,eta1,eta2-(MeS2C)PPh 2]}2, 3, as the final product. The reaction proceeds via a eta2-coordi nation of the C=S fragment to Pd, giving (Pd(PPh3)-[mu,eta1,eta2-(MeS2 C)PPh2]W(CO)5}, 2 as an intermediate. Complexes 2 and 3 are characteri zed by X-ray diffraction analysis.