THE FE-II-FE-IV AND FE-III-FE-V MANIFOLDS IN AN EXPANDED WORLD OF GIFCHEMISTRY

Authors
BARDIN C BARTON DHR HU B ROJASWAHL R TAYLOR DK
Citation
C. Bardin et al., THE FE-II-FE-IV AND FE-III-FE-V MANIFOLDS IN AN EXPANDED WORLD OF GIFCHEMISTRY, Tetrahedron letters, 35(32), 1994, pp. 5805-5808
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
32
Year of publication
1994
Pages
5805 - 5808
Database
ISI
SICI code
0040-4039(1994)35:32<5805:TFAFMI>2.0.ZU;2-K
Abstract
The species responsible for hydrocarbon activation and formation of al kyl chlorides in the Fen and Fe-III-H2O2 and tert-butyl hydroperoxide systems are identified. The importance of the Fe-II-Fe-IV manifold in providing a mechanism which permits the selective functionalization of saturated hydrocarbons by; ionic trapping with chloride, azide, and o ther anions is made manifest. Comparison is made with the Fe-III-Fe-V manifold where ionic trapping is never seen.