NEW PERSPECTIVES IN THE FORMATION OF THE GRIGNARD-REAGENT

Authors
PERALEZ E NEGREL JC CHANON M
Citation
E. Peralez et al., NEW PERSPECTIVES IN THE FORMATION OF THE GRIGNARD-REAGENT, Tetrahedron letters, 35(32), 1994, pp. 5857-5860
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
32
Year of publication
1994
Pages
5857 - 5860
Database
ISI
SICI code
0040-4039(1994)35:32<5857:NPITFO>2.0.ZU;2-T
Abstract
Inhibitors, in very low concentration, inhibit the reaction between 1- bromo-3-methyl-butane and magnesium obtained by vaporization of metal. For such a magnesium derivative, the inhibitors cannot play the role of ''killers'' for active sites. A chain reaction for the formation of the Grignard reagent is proposed.