A NEW PALLADIUM-CATALYZED SYNTHESIS OF 3,4-DISUBSTITUTED COUMARINS FROM 3-ALKENOATES OF ORTHO-IODOPHENOL, PHENYLACETYLENE AND CARBON-MONOXIDE

Authors
CATELLANI M CHIUSOLI GP FAGNOLA MC SOLARI G
Citation
M. Catellani et al., A NEW PALLADIUM-CATALYZED SYNTHESIS OF 3,4-DISUBSTITUTED COUMARINS FROM 3-ALKENOATES OF ORTHO-IODOPHENOL, PHENYLACETYLENE AND CARBON-MONOXIDE, Tetrahedron letters, 35(32), 1994, pp. 5923-5926
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
32
Year of publication
1994
Pages
5923 - 5926
Database
ISI
SICI code
0040-4039(1994)35:32<5923:ANPSO3>2.0.ZU;2-#
Abstract
Palladium(0) has been found to catalyse the reaction of an aromatic ca rbon-iodide bond with carbon monoxide, the triple bond of alkynes and the allylic carbon of an ortho alkenoic chain to form a 3,4-disubstitu ted coumarin ring in satisfactory yield under mild conditions.