The morphology and the electronic structure of heteroepitaxial germani
um layers grown pseudomorphically by solution epitaxy on Si(001) has b
een investigated by scanning tunneling microscopy (STM) and scanning t
unneling spectroscopy (STS). A significant decrease of tunneling curre
nt at a sample voltage of 1.5 V is observed in areas of 0.5 nm diamete
r between dimer rows. This decrease is due to a negative-differential
conductivity at a tunnel diode configuration consisting of a surface d
efect structure of the germanium layer and the STM tungsten tip.