MICHAEL REACTIONS OF SILYLATED NUCLEOPHILES WITH CONJUGATED ENONES ACCOMPANIED BY SILYL GROUP-TRANSFER CATALYZED BY COPPER(I) CHLORIDE UNDER PHOTOIRRADIATION
M. Mitani et Y. Osakabe, MICHAEL REACTIONS OF SILYLATED NUCLEOPHILES WITH CONJUGATED ENONES ACCOMPANIED BY SILYL GROUP-TRANSFER CATALYZED BY COPPER(I) CHLORIDE UNDER PHOTOIRRADIATION, Journal of the Chemical Society, Chemical Communications, (15), 1994, pp. 1759-1760
Photoreaction of conjugated enones with silylated nucleophiles such as
silyl acetals, silyl enol ethers and even an allyl silane resulted in
the formation of Michael adducts accompanied by transfer of the silyl
group.