A description is given of an imaging-based instrument capable of mappi
ng several fundamental properties of analytical plasmas, especially th
e inductively coupled plasma. The plasma fundamental parameters includ
e electron temperature and number density, heavy-particle gas-kinetic
temperature, analyte and argon atom and ion concentrations, and analyt
e emission intensities. These parameters can be measured on the same p
lasma running under identical operation conditions. The techniques to
probe the basic plasma properties include Thomson scattering (for elec
tron concentration and temperature), Rayleigh scattering (for heavy-pa
rticle temperature), computer-aided optical tomography (for three-dime
nsional emission maps), and laser-induced saturated fluorescence (for
analyte and argon atom and ion number densities). A brief description
of these techniques is presented. Also, a new approach to determining
absolute number densities from fluorescence measurements is introduced
. This novel method is based on normalizing a measured fluorescence in
tensity by the room-temperature Rayleigh-scattering signal. (C) 1997 E
lsevier Science B.V.