A. Tiburciosilver et al., OPTICAL BAND-GAP SHRINKAGE IN HIGHLY TRANSPARENT AND CONDUCTING ZNO THIN-FILMS DEPOSITED BY THE PYROSOL PROCESS, Journal of applied physics, 76(3), 1994, pp. 1992-1994
An optical band-gap shrinkage was found in highly transparent and cond
ucting thin films deposited by the Pyrosol Process. The narrowing appe
ars at carrier concentrations which are consistent with a metal-semico
nductor transition. The gap-shrinkage dependence on carrier concentrat
ion is consistent with the model proposed by P E. Schmid [Phys. Rev. B
23, 5531 (1981)] for Si:As and Si:B.