THE PHOTOCHEMICALLY INDUCED OXIDATION OF ANILINE BY HYDROPEROXIDES - AN ELECTRON-PARAMAGNETIC-RESONANCE STUDY .2.

Authors
GROSSI L
Citation
L. Grossi, THE PHOTOCHEMICALLY INDUCED OXIDATION OF ANILINE BY HYDROPEROXIDES - AN ELECTRON-PARAMAGNETIC-RESONANCE STUDY .2., Tetrahedron, 50(31), 1994, pp. 9511-9516
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
31
Year of publication
1994
Pages
9511 - 9516
Database
ISI
SICI code
0040-4020(1994)50:31<9511:TPIOOA>2.0.ZU;2-K
Abstract
The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied. The peculiar radical intermediates, nitr oxides and peroxy radicals, involved in the reaction mechanism were de tected and identified by EPR spectroscopy. The presence of these inter mediates confirm that PhNO is the first product of the oxidation of an iline and the PhNH. radical as its precursor.