The presentation gives a brief overview and description of point defec
ts and extended defects that may be considered to arise from clusterin
g or ordering of point defects. Defect chemistry and the relations bet
ween defect concentrations and transport properties are exemplified an
d illustrated by a review of nonstoichiometry, electrical conductivity
, diffusion of cobalt and oxygen tracers, chemical diffusion, and high
temperature creep of Co1-partial derivativeO.