THERMOKINETICS OF THE ETHYL-ACETATE ACID AND ALKALINE-HYDROLYSIS BY DIFFERENTIAL SCANNING CALORIMETRY

Authors
VILCU R MELTZER V
Citation
R. Vilcu et V. Meltzer, THERMOKINETICS OF THE ETHYL-ACETATE ACID AND ALKALINE-HYDROLYSIS BY DIFFERENTIAL SCANNING CALORIMETRY, Journal of thermal analysis, 41(6), 1994, pp. 1335-1341
Citations number
11
Categorie Soggetti
Chemistry Analytical
Journal title
Journal of thermal analysis → ACNP
ISSN journal
03684466
Volume
41
Issue
6
Year of publication
1994
Pages
1335 - 1341
Database
ISI
SICI code
0368-4466(1994)41:6<1335:TOTEAA>2.0.ZU;2-R
Abstract
The kinetic investigation of thermoanalytical curves for the ethyl ace tate and alkaline hydrolysis, requires tedious calculations of several mathematical expressions, to establish the correlation between the th ermochemical and kinetic parameters. Using the DSC measured data for t he heat flow-temperature dependence of the studied reactions, we have obtained the kinetic bulk parameters and the dependence k = k(T) for t he basic and acid hydrolysis of ethyl acetate.