Quasielastic neutron scattering was used to study the atomistic proton
diffusion mechanism in Yb-doped SrCeO3, a proton conducting perovskit
e, simultaneously in space and time. Proton diffusion consists of a se
quence of trapping and free diffusion events. The free diffusion corre
sponds to the Grotthus mechanism including very fast rotations around
oxygen ions.