Jm. Saiter et al., ALKYD-BASED-THERMOSETTING RESIN - CALORIMETRIC INVESTIGATIONS OF THE CURING PROCESS, Journal of thermal analysis, 41(6), 1994, pp. 1495-1499
In this work, the rate of cure of different oxidative drying oil modif
ied alkyd resins are investigated by DSC measurements. We determine, f
rom the Kissinger equation, the apparent activation energy of the curi
ng process. We show that this activation energy depends on the curing
duration and that these variations lead to the determination of a time
constant, characteristic of the material.