OIL-SOLUBLE ANTIOXIDANT POLYMETHACRYLATES FOR LUBRICANTS

Citation
Sm. Shirodkar et al., OIL-SOLUBLE ANTIOXIDANT POLYMETHACRYLATES FOR LUBRICANTS, Lubrication engineering, 50(8), 1994, pp. 641-646
Citations number
13
Categorie Soggetti
Engineering, Mechanical
Journal title
ISSN journal
00247154
Volume
50
Issue
8
Year of publication
1994
Pages
641 - 646
Database
ISI
SICI code
0024-7154(1994)50:8<641:OAPFL>2.0.ZU;2-P
Abstract
The evaluation of oil soluble, antioxidant bound polymethacrylates use d as viscosity index improver lubricant additives, is described herein . They were synthesized by copolymerization of the antioxidant-dispers ant monomer and alkyl methacrylates. Oxidative stability was determine d by oxidative pressure differential scanning calorimetry, thin film o xidation uptake test and aluminum beaker oxidation text. These tests s how that lubricants containing these polymers show performance advanta ges over commercial polymethacrylates, with additional benefits in oth er viscometric properties such as shear stability and Brookfield visco sity. The antioxidant monomer also serves as a dispersant moiety, thus improving the polymer dispersancy. Binding the antioxidant to the pol ymer ensures the solubility of the antioxidant while eliminating the p ossibility of its volatilization in high temperature environments. The current results suggest that antioxidant-dispersant polymethacrylates have excellent potential as additives in lubricants such as automatic transmission fluids.