We review the experimental status of the study of dynamics of atoms an
d molecules in solids, focussing mainly on the interplay between neutr
on inelastic scattering experiments and theoretical models for the dyn
amics of complex crystals. Particular references are made to studies o
n C60 and the high temperature superconductors. Besides the investigat
ions of phonon dispersion relation using neutron reactors, we also cit
e examples of recent efforts using pulse neutron sources and X-rays fr
om synchrotrons. While single crystals are needed for the determinatio
n of dispersion relation, powder samples are used to obtain the phonon
density of states. Partial density of states corresponding to specifi
c atoms is obtained by their isotopic substitution. We briefly touch u
pon dynamical phenomena other than that described by phonons, such as
diffusion of molecular reorientation, which may be studied by techniqu
es such as computer experiments or neutron quasielastic scattering.