REACTIVITY OF U-H AND U-C BONDS IN ELECTRON-POOR CYCLOPENTADIENYLURANIUM COMPLEXES - ELECTRONIC EFFECTS

Authors
BAUDRY D DORMOND A ABDALLAOUI IA
Citation
D. Baudry et al., REACTIVITY OF U-H AND U-C BONDS IN ELECTRON-POOR CYCLOPENTADIENYLURANIUM COMPLEXES - ELECTRONIC EFFECTS, Journal of organometallic chemistry, 476(1), 1994, pp. 30000015-30000017
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
476
Issue
1
Year of publication
1994
Pages
30000015 - 30000017
Database
ISI
SICI code
0022-328X(1994)476:1<30000015:ROUAUB>2.0.ZU;2-R
Abstract
The organouranium complexes [(C5H4PPh2)3UX] (X = Cl, (1a) X = Me (1b); X = H (1c)) react with BH3 . SMe2. 1a affords the stable [(C5H4PPh2 . BH3)3UCl] (2a). Both 1b and 1c give finally [(C5H4PPh2 . BH3)3UBH4] ( 3). The transient [(C5H4PPh2 . BH3)3UMe] (2b) is observed. 2a and 3 ma y easily be reduced to [(C5H4PPh2 . BH3)3U] (4).