Using Fourier transform infrared absorption measurement with excitatio
n at low temperatures, we have investigated the optical active process
involving higher order bands (HOB) in fast neutron irradiated float-z
one silicon. It is found experimentally that the photo''citation and d
ecay process of the HOB as well as the saturation value of the absorpt
ion intensity are in good agreement with the predictions of the macros
copic barrier model for the slow relaxation of photoexcited carriers c
aused mainly by defect clusters.