The ignition of damp combustible material is considered by treating bo
th the heat transfer and mass transfer in a lumped approach, so that d
iffusive effects are ignored. However the phase changes of water vapou
r to liquid (or vice versa) are included and it is shown that condensa
tion can be important in destabilising reactive material. This is apar
t from any effect due to wet reactions. In particular it is shown that
if a lump of reactive material is initially dry and subcritical, a sl
ight change in the atmospheric humidity can have a marked affect on th
e ignition characteristics of the material.