Jc. Valmalette et Jr. Gavarri, VANADIUM DIOXIDE POLYMER COMPOSITES - THERMOCHROMIC BEHAVIOR AND MODELING OF OPTICAL TRANSMITTANCE, Solar energy materials and solar cells, 33(2), 1994, pp. 135-144
Pigments of vanadium dioxide VO2 were inserted in a polymeric coating
to analyse the optical thermochromic behaviour linked with the semicon
ductor-metal first-order transition at 341 K. Pyranometric equipment w
as adapted to study the variations of artificial solar radiation as a
function of temperature, volume fractions, and grain size. The optical
transition of VO2 pigments was observed and a Beer-Lambert model is p
roposed to interpret the amplitude of flux variations. The thermochrom
ic behaviour of the composite coatings can be optimized.