SYNTHESIS OF SPIRANIC HETEROCYCLES BY IND UCED DECOMPOSITION OF UNSATURATED PEROXIDES

Authors
MONTAUDON E KAPPES R LEMEE L CAMPAGNOLE M BOURGEOIS MJ
Citation
E. Montaudon et al., SYNTHESIS OF SPIRANIC HETEROCYCLES BY IND UCED DECOMPOSITION OF UNSATURATED PEROXIDES, Bulletin de la Societe chimique de France, 131(3), 1994, pp. 253-261
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
131
Issue
3
Year of publication
1994
Pages
253 - 261
Database
ISI
SICI code
0037-8968(1994)131:3<253:SOSHBI>2.0.ZU;2-Z
Abstract
Induced decomposition of unsaturated peroxides in a good hydrogen-dono r solvent leads to the functionalization of the latter. If the peroxid e contains a cycle on the carbon next to the O-O bond, the reaction gi ves spirans with an oxiran, an oxetan or a tetrahydrofuran ring in goo d or even excellent yields.