SYNTHESIS AND FORMULATION OF PESTICIDES B ASED ON N-PHOSPHONOMETHYLGLYCINE

Citation
U. Wyrzykowska et al., SYNTHESIS AND FORMULATION OF PESTICIDES B ASED ON N-PHOSPHONOMETHYLGLYCINE, Przemysl Chemiczny, 73(7), 1994, pp. 273-275
Citations number
NO
Categorie Soggetti
Engineering, Chemical",Chemistry
Journal title
ISSN journal
00332496
Volume
73
Issue
7
Year of publication
1994
Pages
273 - 275
Database
ISI
SICI code
0033-2496(1994)73:7<273:SAFOPB>2.0.ZU;2-Y
Abstract
The genuine method of N-phosphonmethylglicyne (FMG) synthesis from gli cyne, triethylphosphite and formaldehyde was developed and patented by the IPO (Institute of Industrial Organic Chemistry). FMG formes after the acidic hydrolysis of sodium N-diethylphosphonmethylglicate, obtai ned as the result of a two stage synthesis in the contineous two react or cascade. The compound is used as an active substance in numerous pe sticides. Two dimensional mathematical model describing reaction yield versus time was developed to calculate presented optimum synthesis co nditions. On the base of this method, the pilot plant has been built a t the IPO. Synthesis of intermediate product is a continous process, a ll others are batch ones. The plant capacity amounts 100 kg FMG per ba tch. The technology of new herbicides - Perzocyd 220SL and 280SL has a lso been developed.