PREPARATION AND CHARACTERIZATION OF T-CAGE-TYPE S-BRIDGED RH(III)CD(II) POLYNUCLEAR COMPLEXES WITH 2-AMINOETHANETHIOLATE

Authors
KONNO T KAGEYAMA Y OKAMOTO K
Citation
T. Konno et al., PREPARATION AND CHARACTERIZATION OF T-CAGE-TYPE S-BRIDGED RH(III)CD(II) POLYNUCLEAR COMPLEXES WITH 2-AMINOETHANETHIOLATE, Bulletin of the Chemical Society of Japan, 67(7), 1994, pp. 1957-1960
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
7
Year of publication
1994
Pages
1957 - 1960
Database
ISI
SICI code
0009-2673(1994)67:7<1957:PACOTS>2.0.ZU;2-B
Abstract
The reaction of fac(S)-[Rh(aet)3] with Cd-NO3)2 in water gave a T-cage -type S-bridged Rh(III)4Cd(II)3 complex with a ''defective'' [Cd3HO]5 core, [{Rh(aet)3}4Cd3HO](NO3)5 (1). The corresponding T-cage-type Rh( III)4Cd(II)4 complex with a ''complete'' [Cd4O]6+ core, [{Rh(aet)3}Cd4 O](NO3)6 (2), was formed by the reaction of fac(S)-[Rh(aet)3] With a m ixture of Cd(NO3)2 and CdO in water. These complexes were characterize d by a combination of X-ray diffraction and spectroscopic methods.