PHOTOCHEMISTRY OF GAMMA-ALLENYL-SUBSTITUTED CONJUGATED ALKYLIDENECYCLOALKANONES

Authors
SUGIYAMA K YOSHIDA M TSUNO T
Citation
K. Sugiyama et al., PHOTOCHEMISTRY OF GAMMA-ALLENYL-SUBSTITUTED CONJUGATED ALKYLIDENECYCLOALKANONES, Heterocycles, 38(8), 1994, pp. 1721-1726
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
38
Issue
8
Year of publication
1994
Pages
1721 - 1726
Database
ISI
SICI code
0385-5414(1994)38:8<1721:POGCA>2.0.ZU;2-B
Abstract
The photolyses of the gamma-allenyl-substituted conjugated alkylidenec ycloalkanones underwent the intramolecular oxa-Diels-Alder reaction an d the E-Z geometrical isomerization, and for the cyclopentanone posses sing a 3-methyl-1,2-butadienyl group, the intramolecular [2+2] cycload dition also occurred. The oxa-Diels-Alder reaction takes place via pho tochemical process of the Z-enones.