FLOW-INJECTION CHEMILUMINOMETRIC DETERMINATION OF SOME BILE-ACIDS

Citation
Im. Psarellis et al., FLOW-INJECTION CHEMILUMINOMETRIC DETERMINATION OF SOME BILE-ACIDS, Analytica chimica acta, 294(1), 1994, pp. 27-34
Citations number
30
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032670
Volume
294
Issue
1
Year of publication
1994
Pages
27 - 34
Database
ISI
SICI code
0003-2670(1994)294:1<27:FCDOSB>2.0.ZU;2-Q
Abstract
The chemiluminometric oxidation of sulphite by cerium(IV), permanganat e, bromate and dichromate is sensitized by various bile acids. Each re action is investigated by flow-injection chemiluminometric analysis an d conclusions are drawn about the effectiveness of each oxidant. The r eaction with cerium(IV) allows the measurement of 2.00-20.0 mu g ml(-1 ) cholic acid, 2.00-50.0 mu g ml(-1) ursodeoxycholic acid and 3.00-30. 0 mu g ml(-1) chenodeoxycholic and deoxycholic acids with limits of de tection of ca. 1 mu g ml(-1).