STUDIES OF AG(I) COMPLEXES WITH TRIPHENYLPHOSPHINE AND FLUORINATED CARBOXYLATES

Authors
SZLYK E LAKOMSKA I GRODZICKI A
Citation
E. Szlyk et al., STUDIES OF AG(I) COMPLEXES WITH TRIPHENYLPHOSPHINE AND FLUORINATED CARBOXYLATES, Polish Journal of Chemistry, 68(8), 1994, pp. 1529-1534
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
68
Issue
8
Year of publication
1994
Pages
1529 - 1534
Database
ISI
SICI code
0137-5083(1994)68:8<1529:SOACWT>2.0.ZU;2-9
Abstract
Silver(I) complexes with triphenylphosphine and perfluorinated carboxy lic acids residues were synthesized and their thermal and spectroscopi c (IR, C-13, F-19, P-31 NMR) properties studied. Ag(I) appears to be t wo coordinated with triphenylphosphine and 0 bonded unidentate carboxy late. Hexafluoroglutarate binds two metal ions unidentately. The therm al decomposition proceeds at least in two steps and leads to the metal lic silver. The lowest temperature of silver formation has been found for the C9F19COOAgP(C6H5)3.