STRUCTURAL EFFECTS OF HYDROSTATIC-PRESSURE IN ORTHORHOMBIC LA2-XSRCUO4

We have investigated the effect of hydrostatic pressure on the structu re of orthorhombic La2-xSrxCuO4 between 1 atm and 0.6 GPa, using neutr on powder diffraction. Increasing pressure causes the tilt angle of Cu O6 octahedra to decrease, leading to a transition to tetragonal symmet ry. There is a strong compressibility anisotropy for the orthorhombic structure. Order parameters for the transition versus pressure are con sistent with Landau theory for a second-order transition. It is shown that this transition can be universally scaled over (x, T, P) space in the context of Landau theory. We conclude that T(c) varies inversely with the tilt angle and is maximum for the tetragonal structure, i.e., for flat and square CuO2 planes, for this compound.