NEW ACCESS TO CONJUGATED DIENAMIDES AND ENAMIDES - SYNTHESIS OF DEHYDROPIPERNONALINE, PIPERNONALINE AND RELATED BIOLOGICALLY-ACTIVE AMIDES

Citation
H. Kaga et al., NEW ACCESS TO CONJUGATED DIENAMIDES AND ENAMIDES - SYNTHESIS OF DEHYDROPIPERNONALINE, PIPERNONALINE AND RELATED BIOLOGICALLY-ACTIVE AMIDES, Synlett, (8), 1994, pp. 607-608
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
8
Year of publication
1994
Pages
607 - 608
Database
ISI
SICI code
0936-5214(1994):8<607:NATCDA>2.0.ZU;2-L
Abstract
A new method for the synthesis of conjugated dien- and enamides by pal lladium-catalyzed coupling reaction of (E)-beta-bromo-acrylamides with alkenyl- and alkylboronates is reported. This procedure provided some biologically active, naturally occurring unsaturated amides, such as dehydropipemonaline, pipernonaline and other related alkaloids, in one -pot.