NEW ACCESS TO CONJUGATED DIENAMIDES AND ENAMIDES - SYNTHESIS OF DEHYDROPIPERNONALINE, PIPERNONALINE AND RELATED BIOLOGICALLY-ACTIVE AMIDES
Citation
H. Kaga et al., NEW ACCESS TO CONJUGATED DIENAMIDES AND ENAMIDES - SYNTHESIS OF DEHYDROPIPERNONALINE, PIPERNONALINE AND RELATED BIOLOGICALLY-ACTIVE AMIDES, Synlett, (8), 1994, pp. 607-608
Categorie Soggetti
Chemistry Inorganic & Nuclear
SICI code
0936-5214(1994):8<607:NATCDA>2.0.ZU;2-L
Abstract
A new method for the synthesis of conjugated dien- and enamides by pal
lladium-catalyzed coupling reaction of (E)-beta-bromo-acrylamides with
alkenyl- and alkylboronates is reported. This procedure provided some
biologically active, naturally occurring unsaturated amides, such as
dehydropipemonaline, pipernonaline and other related alkaloids, in one
-pot.