SYNTHESIS OF ALPHA-ALKINYLENAMINES BY TRIMETHYLSILANOLATE-INDUCED ALPHA-DEPROTONATION OF PROPYNE IMINIUM SALTS

Authors
BRUNNER M REINHARD R RAHM R MAAS G
Citation
M. Brunner et al., SYNTHESIS OF ALPHA-ALKINYLENAMINES BY TRIMETHYLSILANOLATE-INDUCED ALPHA-DEPROTONATION OF PROPYNE IMINIUM SALTS, Synlett, (8), 1994, pp. 627-628
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1994
Pages
627 - 628
Database
ISI
SICI code
0936-5214(1994):8<627:SOABTA>2.0.ZU;2-B
Abstract
Iminium salts bearing an alpha-CH group are efficiently deprotonated w ith sodium trimethylsilanolate in a non-aqueous reaction medium. In th is manner, little known alpha-alkinylenamines can be obtained from pro pyne iminium triflates.