INTRAMOLECULAR CONJUGATE ADDITION OF ALLYLIC TRICHLOROACETIMIDATES TOCYCLOALKENYL SULFONES - A REGIOSPECIFIC AND STEREOSELECTIVE SYNTHESISOF AMINO ALCOHOL DERIVATIVES

Authors
LI C FUCHS PL
Citation
C. Li et Pl. Fuchs, INTRAMOLECULAR CONJUGATE ADDITION OF ALLYLIC TRICHLOROACETIMIDATES TOCYCLOALKENYL SULFONES - A REGIOSPECIFIC AND STEREOSELECTIVE SYNTHESISOF AMINO ALCOHOL DERIVATIVES, Synlett, (8), 1994, pp. 629-630
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1994
Pages
629 - 630
Database
ISI
SICI code
0936-5214(1994):8<629:ICAOAT>2.0.ZU;2-F
Abstract
Allylic trichloroacetimidates 2a-c generated in situ undergo intramole cular conjugate addition to vinyl sulfones to afford oxazolines 3a-c. Acid hydrolysis of the oxazolines generate vicinal cis-amino alcohol d erivatives of five and six-membered rings.