SCHIFF-BASE NUCLEOPHILES - PROGRESS TOWARDS THE GENERAL APPLICATION OF ORGANOIRON COMPLEXES IN AMINO-ACID SYNTHESIS

Authors
GENET JP HUDSON RDA MENG WD ROBERTS E STEPHENSON GR THORIMBERT S
Citation
Jp. Genet et al., SCHIFF-BASE NUCLEOPHILES - PROGRESS TOWARDS THE GENERAL APPLICATION OF ORGANOIRON COMPLEXES IN AMINO-ACID SYNTHESIS, Synlett, (8), 1994, pp. 631-634
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1994
Pages
631 - 634
Database
ISI
SICI code
0936-5214(1994):8<631:SN-PTT>2.0.ZU;2-3
Abstract
Schiff base nucleophiles have been employed with cationic cyclohexadie nyliron pi-complexes to gain access to intermediates that are suitable for elaboration into new amino acid structures. Addition to a vinyl s ubstituted cation formed a quaternary centre in the first example of t his mode of addition. The results demonstrate that Schiff base nucleop hiles have appropriate basicity/reactivity properties for use with tri carbonyliron complexes.