Jf. Meng et al., RAMAN-SCATTERING FROM PBTIO3 OF VARIOUS GRAIN SIZES AT HIGH HYDROSTATIC PRESSURES, Journal of physics. Condensed matter, 6(32), 1994, pp. 6543-6548
The Raman spectra for PbTiO3 of various grain sizes at different hydro
static pressures have revealed that the soft E(1TO) phonon mode appear
s to undergo a red shift in frequency and increases in linewidth with
decreasing grain size, and that the pressure dependences of the soft m
ode in nanocrystalline PbTiO3 can be correlated with the diffuse phase
transition.