COMPUTER-SIMULATION OF THE ION ESCAPE FROM HIGH-ENERGY ELECTRON TRACKS IN NONPOLAR LIQUIDS

Citation
Lda. Siebbeles et al., COMPUTER-SIMULATION OF THE ION ESCAPE FROM HIGH-ENERGY ELECTRON TRACKS IN NONPOLAR LIQUIDS, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(8), 1997, pp. 1619-1627
Citations number
49
Categorie Soggetti
Chemistry Physical
ISSN journal
10895639
Volume
101
Issue
8
Year of publication
1997
Pages
1619 - 1627
Database
ISI
SICI code
1089-5639(1997)101:8<1619:COTIEF>2.0.ZU;2-L
Abstract
The number of ions escaping from recombination in high-energy electron tracks in saturated hydrocarbon liquids is calculated and compared wi th experimental results from the literature. The initial track structu re is obtained by bringing the details of the electron scattering into account. The number of positive ions and electrons that escape from c harge recombination is obtained from a computer simulation of the traj ectories of the positive ions and the electrons. The probability that the charges escape from each other is seen to change appreciably with the energy of the primary high-energy electron. The thermalization dis tance distribution of the electrons in the track is obtained by compar ing the calculated results with those from experiments. The influence of external electric fields on the escape of ions is considered.