INELASTIC ELECTRON-TUNNELING SPECTROSCOPY OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE (BEDT-TTF) COMPOUNDS

Citation
C. Garrigoulagrange et al., INELASTIC ELECTRON-TUNNELING SPECTROSCOPY OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE (BEDT-TTF) COMPOUNDS, Chemical physics letters, 225(4-6), 1994, pp. 297-302
Citations number
20
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
225
Issue
4-6
Year of publication
1994
Pages
297 - 302
Database
ISI
SICI code
0009-2614(1994)225:4-6<297:IESOB>2.0.ZU;2-0
Abstract
Inelastic electron tunneling spectra of thin films of bis(ethylenedith io)tetrathiafulvalene (BEDT-TTF) and its salts: a low temperature supe rconductor K-(BEDT-TTF)2Cu(NCS)2 and an insulator (BEDT-TTF)2Mo6O19 ar e measured at 4.2 K in the range 230-1650 cm-1 and compared with infra red spectra of the same compounds at room temperature. The obtained vi brational bands are assigned following theoretical normal mode calcula tions. Electron-molecular vibration coupling theory of charge-transfer organic compounds is extended to the case of electron tunneling spect ra.