Highly oriented heteroepitaxial diamond films grown on silicon (001) s
ubstrates were investigated by photothermal displacement spectroscopy
at transient thermal gratings. Lateral thermal diffusivities were meas
ured as a function of the height within the 90 mum thick films. A stro
ng diffusivity variation was observed from less than 1 cm2 s-1 near th
e substrate interface up to 10 cm2 s-1 in the top growth region, which
is about 80% of that for single-crystal type IIa diamond. The results
are compared with those obtained from fibre-textured diamond films. T
he structural properties are characterized using micro-Raman spectrosc
opy.