H. Stapelfeldt et al., AUTOIONIZING STATES OF NEGATIVE-IONS IN STRONG RESONANT LASER FIELDS - THE NEGATIVE RUBIDIUM ION, Physical review. A, 50(2), 1994, pp. 1618-1626
We have performed an experimental study of the atomic system Rb-, for
which the ground state 5s2 is coupled to the autoionizing state 5p(1/2
)6s by means of a strong resonant laser field. The investigations are
based on irradiation of Rb- with intense (I less-than-or-equal-to 1.5
x 10(10) W/cm2) laser pulses of duration approximately 1 ns. Single-ph
oton detachment of Rb- is suppressed due to the Fano interference betw
een transitions directly to the continuum and transitions via the auto
ionizing state. In contrast, two-photon absorption is at the same time
resonantly enhanced since no such destructive interference is present
in this process. These observations constitute experimental evidence
of general features predicted from theoretical considerations of autoi
onizing states in strong laser fields. Furthermore, we discuss the rol
e of autoionizing states in multiphoton double-ionization processes. E
lectron spectroscopy has been used to show that double ionization of R
b- primarily is the result of a sequential removal of the two electron
s via an excited Rb state. The perspectives for direct two-electron io
nization in negative ions are briefly discussed.