The removal of five volatile organic chemicals (VOCs) was evaluated by
passing the contaminated water once through a hollow-fiber-membrane m
odule that received a countercurrent flow of air recycled from an ultr
aviolet (UV) photooxidation chamber. VOC removal was measured experime
ntally under a variety of operating conditions. The results compared f
avorably with the behavior predicted by a mathematical model of the pr
ocess. When operated as a closed-loop process, the photooxidation of t
he VOCs in the gas phase has several advantages over conventional air-
stripping with off-gas treatment: the end products are reabsorbed back
into the water flow; no exhaust gases are released to the atmosphere;
and no adsorbent regeneration or disposal costs are incurred.