NEW SYNTHESES OF MIXED PEROXIDES UNDER GIF-BARTON OXIDATION OF ALKYLBENZENES, CONJUGATED ALKENES AND ALKANES - A FREE-RADICAL MECHANISM

Authors
MINISCI F FONTANA F ARANEO S RECUPERO F
Citation
F. Minisci et al., NEW SYNTHESES OF MIXED PEROXIDES UNDER GIF-BARTON OXIDATION OF ALKYLBENZENES, CONJUGATED ALKENES AND ALKANES - A FREE-RADICAL MECHANISM, Journal of the Chemical Society, Chemical Communications, (16), 1994, pp. 1823-1824
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
16
Year of publication
1994
Pages
1823 - 1824
Database
ISI
SICI code
0022-4936(1994):16<1823:NSOMPU>2.0.ZU;2-Q
Abstract
Syntheses of mixed peroxides are performed under Gif oxidation of alky laromatics, electron-rich conjugated alkenes (styrene, alpha-methylsty rene) or cyclohexane and acrylonitrile; chemical and kinetic evidence support a free-radical redox chain mechanism.