TITANIUM-SUBSTITUTED ZEOLITE BETA(TI-AL-BETA)-CATALYZED EPOXIDATION OF OCT-1-ENE WITH TERT-BUTYL HYDROPEROXIDE (TBHP)

Authors
SATO T DAKKA J SHELDON RA
Citation
T. Sato et al., TITANIUM-SUBSTITUTED ZEOLITE BETA(TI-AL-BETA)-CATALYZED EPOXIDATION OF OCT-1-ENE WITH TERT-BUTYL HYDROPEROXIDE (TBHP), Journal of the Chemical Society, Chemical Communications, (16), 1994, pp. 1887-1888
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
16
Year of publication
1994
Pages
1887 - 1888
Database
ISI
SICI code
0022-4936(1994):16<1887:TZBEO>2.0.ZU;2-Q
Abstract
Titanium substituted zeolite beta(Ti-Al-beta) catalyses the epoxidatio n of oct-1-ene with TBHP; high selectivities to epoxide (92-100%) are observed when the Bronsted acid sites are neutralized by ion exchange with alkali or alkaline earth metal ions.