THE EFFECT OF RUO2 TIO2 RATIO ON THE RATE OF AN OUTER-SPHERE ELECTRON-TRANSFER REACTION ON MIXED-OXIDE ELECTRODES/

Authors
TOMCSANYI L MOLNAR F LISZI J DEBATTISTI A
Citation
L. Tomcsanyi et al., THE EFFECT OF RUO2 TIO2 RATIO ON THE RATE OF AN OUTER-SPHERE ELECTRON-TRANSFER REACTION ON MIXED-OXIDE ELECTRODES/, Electrochimica acta, 39(11-12), 1994, pp. 1923-1926
Citations number
22
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
39
Issue
11-12
Year of publication
1994
Pages
1923 - 1926
Database
ISI
SICI code
0013-4686(1994)39:11-12<1923:TEORTR>2.0.ZU;2-S
Abstract
The apparent heterogeneous rate constants can be determined by a speci al cv technique in solutions containing both the oxidized and the redu ced forms of a redox couple. The electrode materials are characterized by the difference between the k(ox)(0) and k(red)(0). The effect of R uO2/TiO2 ratio on the electrochemical effective surface area and the a pparent rate constants of a redox system are investigated. The optimal composition of the RuO2/TiO2 electrode seems ta be in the 0.6-0.9 RuO 2 mole fraction range.