Spectroscopic ellipsometry is used to examine the microstructure of tw
o buried SixGe1-x alloy films grown by molecular beam epitaxy. In each
case the optical measurements show these heterostructure materials to
differ significantly in composition and thickness from those which we
re intended. These discrepancies indicate that there is substantial mi
xing of species across interfaces. Spectroscopic ellipsometry, which i
n principle could be performed in situ to monitor the growth of such m
aterials, is shown to provide a quick diagnostic of this intermixing.